1) Download an app called Superbeam from the Play Store
2) Open the app and choose the file you want to share. Click Send
3) Change the sharing option to WEB (Just swipe towards the left)
4) Now turn on your PS Vita and connect to the WiFi network shown in your phone
5) Open the web browser of your PS Vita
6) Type the address shown in your phone on your PS Vita
7) A web page will open with the names of the file you have chosen to share.
8) Click the files name and you'll get option to download the file
Edit: I forgot to mention that you DON'T need internet access for this method of transferring files.
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